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The devil’s in the details

Pam’s paints weren’t cheap; they were by reputable manufacturers. But she was caught in the maze of historic names and convenience mixes.

Spring Allee, 14X18, oil on archival canvasboard, available.

Last week my students did a green-mixing exercise. Pam Otis had a tough time getting the proper mixes out of the yellows on her palette. After class, she sent me photos of every yellow she had. I spent an instructive half-hour happily looking up each tube.

I know, generally, what’s in colors, but different manufacturers have different ways of getting to that point. If the paint tube isn’t marked (or has been crimped or damaged so you can’t read the tiny type), you must research the paint on the manufacturer’s site. Often, you’ll learn something, because paints are constantly changing.

Vineyard, 30X40, oil on canvas, available.

Some changes are due to market conditions. PO49, quinacridone gold, was a very useful color (as all the quinacridones are). However, it was discontinued by the auto industry in 2001. The fine arts market for pigments is miniscule, so PO49 disappeared. Most modern quinacridone golds are convenience mixes of quinacridone orange (PO48) and nickel azo yellow (PY150). Both are perfectly fine pigments, but they work differently in mixes than the original pigment.

Other substitutions are more inscrutable. The siennas are ancient pigments made of dirt—a mixture of iron and manganese oxides, to be specific. In its natural state, this pigment is yellow-brown and called raw sienna. Cooked, it turns red and is burnt sienna. Along with ochre and umber, raw sienna was among the first pigments ever used by prehistoric humans. It has been used ever since, because it’s cheap, plentiful, harmless, and doesn’t fade. Modern earth pigments are all manufactured analogues, but are chemically indistinguishable from the old mined ore.

I have no idea why Winsor & Newton substitutes a combination of burnt sienna (PR101) and yellow ochre (PY42) for ordinary raw sienna. But that may be why some yellow ochres and raw siennas are indistinguishable out of the tube.

Bracken fern, 9X12, oil on archival canvasboard, available.

A hue is a blend of less-expensive pigments. There is nothing inherently wrong with hues, but they don’t behave the same as the pigments they’re named after. “Cadmium yellow hue” may look like cadmium yellow coming out of the tube, but it makes insipid greens.

Then there is the stuff that watercolorists call Gamboge. The real thing came from tapping the latex of the Garcinia, or Gamboge Tree. It’s a beautiful, transparent, non-staining orange-yellow, but it’s also extremely fugitive (as vegetable dyes tend to be). So, manufacturers substitute other pigments and call the result New Gamboge. The most common ingredients are nickel azo yellow and anthrapyrimidine yellow (PY108) However, there are as many formulas as there are manufacturers, and every combination behaves differently.

Spring Greens, 8X10, oil on archival canvasboard, available.

The origins of Indian yellow have long been disputed. It was said that it was extracted from the urine of cows fed a diet of only mango leaves. 20th century, art historians doubted this, but recent chemical analysis of historic samples confirm the source as animal urine.

We now reject the idea of starving cows to create pretty pigments (although euxanthic acid can be synthesized in the lab). Today we use combinations of nickel azo, hansa yellow, and quinacridone burnt orange. It’s a terrific paint for making dark greens. The trouble, again, is that every manufacturer has its own formula for Indian Yellow.

Pam’s paints weren’t cheap; they were by reputable manufacturers. But she was caught in the maze of historic names and convenience mixes. Knowing how to read the CII code on your paint tube is important.

The CII code consists of two letters and some numbers. Most paints start with a “P” which means it’s a pigment, not a dye. The next letter is the color family:  PR is red, PY is yellow, etc. The number is the specific pigment included in the tube.

Save this link somewhere accessible from your phone. You’ll need it when you shop. This pigment guide was built for watercolors but is generally true across all media. 

Cheap paint is a false economy

Don’t skimp on paint quality, or you’ll defeat yourself from the outset.

Ogunquit, by Carol L. Douglas. If the pigment isn’t in the paint to start with, you can’t magically enhance it. 

When I send supply lists, I suggest brands. These are Golden for acrylics, QoR for watercolor, and RGH or Gamblin for oils. In pastels, there is too much variation in hardness for a blanket recommendation, but I like Unison myself. Of course, nobody’s paying me for these endorsements; they’re just my preferences.

That doesn’t mean these are the only good art supplies out there. They have a combination of pigment load and handling characteristics that I like. There are many excellent makers of paint out there. They come in a variety of price points, but price is not the sole indicator of quality.

Late October, Beauchamp Point, by Carol L. Douglas

There are an equal number of horrible paints on the market. You might think you’ve saved a few bucks, but they’re an expensive mistake, one that will cost you time in learning. Don’t skimp on paint quality, or you’ll defeat yourself from the outset. Instead, cut down on the number of colors you buy.

All paints (and pastels) consist of pigment and a binder. There are differences in the quality of binders, in the amount of pigment the manufacturer uses, and how the pigments are stabilized. There may be filler added, or drying agents.

Most major paint brands in the US subscribe to voluntary associations of quality control. (RGH is an exception; that’s too bad, because their paint is excellent.) The most well-known is Colour Index International (CII), a database dating back to 1925. It contains over 27,000 individual products sold under 13,000 different product names. This standard classification system gives you the facts about the pigments in your tube.

Autumn Farm, by Carol L. Douglas

Just as Benjamin Moore uses names like Yukon Sky to peddle grey paint, art paints are often marketed with evocative names. These names appeal to our sense of tradition, even when the old paint has no relationship to its namesake. If you buy Naples Yellow thinking you’re buying an historic pigment, think again: the modern paint is a convenience mix replacing the historic (and toxic) lead antimonate.

Expect to find, at minimum, the following information on the label of your paint tube:

  • Manufacturer’s name or common name for the color.
  • The CII number and, sometimes, the name of the pigment(s).
  • The manufacturer’s lightfastness or permanence rating.

The CII code consists of two letters and some numbers. Most paints start with a “P” which means it’s a pigment, not a dye. The next letter is the color family:  PR is red, PY is yellow, etc. The number is the specific pigment included in the tube.

Save this link somewhere accessible from your phone: https://www.handprint.com/HP/WCL/waterfs.html

You’ll need it when you shop. This pigment guide was built for watercolors but is generally true across all media. (Watercolor is the canary in the coalmine of pigments). All painters should understand lightfastness, transparency, and color shift. Granulation, bloom and diffusion, however, are watercolor-specific issues. 

Winch, by Carol L. Douglas

When you compare paints with the same names, check their CIIs. Are they the same or different pigments? A “hue,” is made of a blend of less-expensive pigments. There is nothing inherently wrong with hues, but they don’t behave the same as the pigments they’re named after. For example, “cadmium yellow hue” may look like cadmium yellow coming out of the tube, but it makes insipid greens.

There’s little to be gained by buying a hue mimicking a more expensive pigment. If you are comfortable painting with a hue, then learn what’s in it and mix it yourself. You always have the greatest flexibility by working with pure pigments (rather than mixes) out of the tube.

Most manufacturers include their own lightfastness ratings on the tube. This is a measure of how quickly the color fades. If it’s not listed, look it up.

The series number tells you the price. Are pricier pigments better? Not by a long shot. Twentieth-century manufacturing gave us a new world of inexpensive pigments, which tend to be less toxic, higher in chroma and lightfast.

I’m thinking about supply lists because it’s time to send them out for Find Your Authentic Voice in Plein Air in Tallahassee, Florida, in early November. There are enough students to go, but there are still openings, so I’d be excited if you signed up. s

From there on in, it’s all Zoom, Zoom, Zoom until the snow stops flying. The Tuesday morning class is sold out; there are still openings for Monday night Zoom classes.

Monday Morning Art School: mixing greens

The rookie error for summer is to paint all foliage using the same basic color. You lose more points if it’s sap green.
Hazy mountain afternoon: Keuka Lake, by Carol L. Douglas. Available.
I have a student who reacts to my pulling out black paint by making the sounds of a rattlesnake at me. She’s been fully inculcated into the idea that black should be banned.
Michael Wilcox published a famous watercolor pigment guide called Blue and Yellow Don’t Make Green. Most of what it tells you can now be found on the internet, but it’s where I first got the idea to add back the banned black.
His point was that there are many routes to the same destination, and that to really mix colors, you need to understand what pigments you’re using, not work from trade names for colors. Consider sap green, for example—a staple of many plein air painters’ toolkit. It’s really a convenience mix made of a phthalo blue and some kind of yellow. The same is true of Hooker’s Green.
Chart courtesy of Victoria Brzustowicz
The single-pigment (‘true’) greens available are chromium oxide green, viridian, and cobalt green. Chromium oxide green is a lovely, heavy, natural green. Unfortunately, it outweighs everything it’s mixed with. Viridian and cobalt green are lovely, but expensive. Beware viridian hue—it’s just another phthalo in disguise.
By now, foliage has settled into a deeper, more uniform tone. The rookie error of August is to paint all your greens using the same basic color, modulating lighter or darker for highlights and shadows. You’ll have much more life in your trees if you know all the different ways you can get to leafy green. One of the most useful greens is black plus cadmium yellow lemon (or Hansa yellow).
Mixed greens, in oils.
The best way to navigate the colors of foliage is to avoid greens out of a tube altogether. A system of paired primaries gives you more options, avoiding the acidity of phthalo, the weight of chromium oxide green, or the soul-sucking darkness of sap green.
In my experience, bad paint mixing causes paintings to go wrong faster than anything else. Constantly over-daubing to modulate the paint color distorts the original drawing and makes a grey mush. If you’re confident of the color, you can apply it fast and accurately.
I make my greens on a matrix, which I’ve shown you both mixed (at top) and on a chart (below). I’m leaving for Castine Plein Air, but if I were teaching, I’d be drilling my students on green this week.
Swatches by Jennifer Johnson
First mix greens according to the chart, and then modulate your resulting greens with tints (meaning a mix of white and a color). The specific tints are unimportant, but the most useful one for landscape is a mix of white, ultramarine and quinacridone violet, making a pale lavender. It is great for atmospheric perspective.
Note that blue/black pigments are much stronger than the yellows. You need about half the amount of blue or black as you do yellow.
Your assignment is to hit paint swatches as closely as you can. 
The second exercise involves stopping at your local hardware store for a few paint swatches. These are Benjamin Moore brand, but you should be able to find similar ones elsewhere. There are two off-whites: one cool and one warm. There’s yellow, green, and two soft blues. Your assignment is to mix until you think you’ve hit the exact color. Then put a dot of it on the card to see how close you got. (If you’re working in watercolor, the dot goes on paper instead.)
Jennifer’s neutral swatches, up close.
I also have my students make neutrals using combinations of ultramarine blue with burnt sienna and raw sienna. I use ultramarine blue and burnt sienna as my standard dark-neutral, because it can go to the warm or cool side depending on how it is mixed. Raw sienna plus ultramarine is my go-to starting point for granite and the sands of our northern beaches.

Buying too many paints is a classic rookie error

Mix, don’t buy, your colors.
Grand Bahama palms, by Carol L. Douglas. There’s really no reason to buy any greens for oil painting, and just one will do for watercolors.

“[Our] watercolor instructor wants us to buy every color we need for a painting. I think it is unnecessary because you can mix colors to get the same or similar results. What is your opinion?” a reader asked.

I ask my students to buy a specific palette based on paired primaries, but that is very different from asking them to buy a specific pigment for a painting. An artist who regularly switches out his or her paints is akin to a pianist who rearranges the keys for each song.
Buying too many paints is a classic rookie error. It’s easy to get pulled into a revel of paint-buying when you’re feeling unsure. We’ve all done it.
Tomatoes, by Carol L. Douglas, was painted without any red or green on my palette. The red you see is violet and orange.
The clear leader in marketing romance, as Handprintcalls it, is Daniel Smith. I sometimes go to their website to feel the verbiage wash over me. “The mineral for our Red Jasper Genuine comes from India’s Gwalior region and is colored a rich red from iron. Historically it was often carved as amulets, vases and other decorative items.  India’s red jasper was one of stones used to beautifully embellish the Taj Mahal with other semi-precious stones that were carved and inlaid into the white marble in curvilinear flower forms… Spiritually, red jasper is associated with the base or root chakra and helps to ground and energize/heal the body and provide balance and protection.”
I can infer it’s an iron oxide red. Not as romantic, but cheap and commonly available.
Headlights, by Carol L. Douglas. No black here, either. It’s ultramarine blue and burnt sienna.
Daniel Smith loves to tell people how to use each pigment: “Red Jasper Genuine is a wonderful color for landscapes, birds like the male common chaffinch and reddish egret, as well as animals who have a medium to light reddish coat like the red panda.” I imagine a studio with hundreds of tubes of their paint, in careful rows, tagged, “for sunlit shadows,” or “for moonlight,” or “for powerful, monolithic shapes.” It’s all very entertaining and poetic, but will do nothing for your painting.  
Get tough, Reader. Ask your teacher the purpose in all these single-use paints. If the answer isn’t satisfactory, it’s time to find a new instructor. Mixing color is so integral to painting that a class that avoids it isn’t going to teach you anything useful.
Ogunquit rocks, by Carol L. Douglas. All four paintings were done with the same palette.
On the heels of that note came another. “Do you teach color mixing by visual understanding or by paint name?” a reader asked. “The moment I understood that there was no such thing as red, blue, and yellow, the world changed and it became possible to see the nature of each color.”
I teach color mixing (as distinct from color theory) on the basis of pigment. I’ve developed, over the years, a stable palette that gives me the widest gamut (range) of color tones. They don’t include convenience mixes.
These are combinations of two or more pigments to approximate a different pigment. Many of them were developed as substitutes for antiquated pigments that may have been pulled from the market because they’re fugitive or toxic. They are limited, because:
  • Every time you add another color to a mix, you’re adding overtones;
  • You can easily make the mix yourself if you should need it and;
  • They’re inconsistent. Their marketing name tells you nothing.

How do I know what pigment(s) are in my paint? They’re written on the tubes, in tiny letters. Here’s a quick primer on how to read a paint tube. It sounds complicated, but it’s nothing compared to the frustration of painting with the wrong materials.